湖南电力 ›› 2024, Vol. 44 ›› Issue (3): 48-54.doi: 10.3969/j.issn.1008-0198.2024.03.007

• 特约专栏: 输变电设备数字化运检技术 • 上一篇    下一篇

Pt-HfSe2检测SF6分解组分的传感机理研究

胡雄雄1, 邹铃尉1, 张小林1, 崔豪2   

  1. 1.国网重庆市电力公司检修分公司,重庆 400039;
    2.西南大学人工智能学院,重庆 400715
  • 收稿日期:2024-04-01 修回日期:2024-05-05 出版日期:2024-06-25 发布日期:2024-07-10
  • 通信作者: 崔豪(1991),男,副教授,主要从事输配电设备运行状态评估和绝缘在线监测的研究工作。
  • 作者简介:胡雄雄(1990),男,工程师,主要从事变电运维研究工作。
  • 基金资助:
    国家自然科学基金项目(52207175)

Sensing Mechanism of Pt-HfSe2 for Detecting SF6 Decomposition Components

HU Xiongxiong1, ZOU Lingwei1, ZHANG Xiaolin1, CUI Hao2   

  1. 1. State Grid Chongqing Ultra High Voltage Company, Chongqing 400039, China;
    2. College of Artificial Intelligence, Southwest University, Chongqing 400715, China
  • Received:2024-04-01 Revised:2024-05-05 Online:2024-06-25 Published:2024-07-10

摘要: 通过检测SF6分解组分可有效评估电气设备设备运行状态,进而保障设备的安全稳定运行。基于第一性原理提出Pt掺杂HfSe2(Pt-HfSe2)检测SO2和SOF2,研究Pt-HfSe2对两种气体组分的吸附和传感机理,探究其作为电阻型气体传感器评估SF6电气设备运行状态的应用潜力。结果表明,Pt-HfSe2对SO2的吸附性能强于对SOF2的,同时,两种气体在Pt-HfSe2表面具有较好的脱吸附性能,能够保证该传感材料的重复使用。Pt-HfSe2具备开发为新型SO2和SOF2气体传感器件的条件,可用于评估SF6电气设备的运行状态,为研究HfSe2基气体传感器提供了理论支持,为新型纳米传感器件应用于电力设备故障诊断提供新思路。

关键词: Pt-HfSe2, 第一性原理, 气敏传感机理, SF6分解组分

Abstract: :By detecting SF6 decomposition components, the operating state of the equipment can be effectively evaluated, and the safe and stable operation of the equipment can be guaranteed. Based on the first principles, Pt-HfSe2 is proposed to detect SO2 and SOF2, and the adsorption and sensing mechanism of PT-HFSE2 on the two gas components is studied, so as to explore its application potential as a resistive gas sensor to evaluate the operating status of SF6 electrical equipment. The results show that the adsorption performance of Pt-HfSe2 on SO2 is stronger than that of SOF2, and the two gases have better desorption performance on the surface of Pt-HfSe2, which can ensure the reuse of the sensor material. Pt-HfSe2 has the conditions to be developed as new SO2 and SOF2 gas sensors, which can be used to evaluate the operating status of SF6 electrical equipment, providing theoretical support for the research of HFSE2-based gas sensors, and providing a new idea for the application of new nano-sensor components to the fault diagnosis of power equipment.

Key words: Pt-HfSe2, first-principles theory, gas sensing mechanism, SF6 decomposed species

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